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selenous acid : ウィキペディア英語版
selenous acid

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Selenous acid (or selenious acid) is the chemical compound with the formula H2SeO3. Structurally, it is more accurately described by (HO)2SeO. It is the principal oxoacid of selenium; the other being selenic acid.
==Formation and properties==
Selenous acid is analogous to sulfurous acid, but it is more readily isolated. Selenous acid is easily formed upon the addition of selenium dioxide to water. As a crystalline solid, the compound can be seen as pyramidal molecules that are interconnected with hydrogen bonds. In solution it is a diprotic acid:〔Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.〕
: + (pKa = 2.62)
: + (pKa = 8.32)
It is moderately oxidizing in nature, but kinetically slow. In 1 M :
: + 4 + 4 e Se + 3 (''E''o = +0.74 V)
In 1 M :
: + 4 e + 3 Se + 6 (''E''o = −0.37 V)
It is used in organic synthesis for the synthesis of 1,2-diketones (e.g. glyoxal).〔(“Glyoxal Bisulfite” ), Organic Syntheses, Collected Volume 3, p.438 (1955).〕

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